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Phosphonate-based iron complex for a cost-effective and long
A promising metal-organic complex, iron (Fe)-NTMPA 2, consisting of Fe (III) chloride and nitrilotri- (methylphosphonic acid) (NTMPA), is designed for use in aqueous iron redox flow...
Improving the electrochemical characteristics and performance of a
Abstract At present, the all-iron redox flow batteries (RFBs) have greater application potential due to high accessibility of electrolytes compared to traditional RFBs. Meanwhile, although electroactive
A Neutral Zinc–Iron Flow Battery with Long Lifespan and High Power
Herein, sodium citrate (Cit) was introduced to coordinate with Zn 2+, which effectively alleviated the crossover and precipitation issues. Meanwhile, the redox species exhibited
Non-nitrogenous bisphosphonate as a ligand for an all-soluble iron
We present the first approach using a non-nitrogenous bisphosphonic acid, 1-hydroxyethylidene-1,1-diphosphonic acid (HEDP; etidronic acid), as a ligand to synthesize an Fe
A high-capacity and ultra-stable neutral all-iron redox flow battery
In this work, we introduce the first all-soluble all-iron RFB based on iron as the same redox-active element but with different coordination chemistries in alkaline aqueous system.
Using ferrous-oxidizing bacteria to enhance the performance of a pH
Among various redox flow batteries (RFBs), the all-iron RFBs have greater application potential due to high accessibility of electrolytes. However, the potential of microaerobic ferrous-oxidizing bacteria
New All-Liquid Iron Flow Battery for Grid Energy Storage
What makes this battery different is that it stores energy in a unique liquid chemical formula that combines charged iron with a neutral-pH phosphate-based liquid electrolyte, or energy
A high-capacity and ultra-stable neutral all-iron redox flow battery
Herein, an ethylenediamine tetramethylenephosphonic (EDTMP) acid-coordinated Fe ion [Fe (EDTMP)], that reaches 1.5 M solubility under mild conditions (pH ≈ 8), is designed as anolyte to overcome the
Near to neutral pH all-iron redox flow battery based on
We demonstrate a redox flow battery at a near to neutral of pH 8.6 using nontoxic iron-coordination compounds as redox carriers in both negative and positive electrolytes.
Aqueous iron-based redox flow batteries for large-scale energy storage
Iron-based ARFBs rely on the redox chemistry of iron species to enable efficient and cost-effective energy storage. Understanding the fundamental electrochemical principles of these
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